Electronic configuration of copper

29Cu
Copper
[Ar] 3d10 4s1
Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s1

Electrons in each shell

2K shell8L shell18M shell1N shell

Copper has 29 electrons arranged as 2, 8, 18, 1 across 4 shells, which is why it sits in period 4.

How to write it

Electrons fill orbitals in order of increasing energy: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p… Each s orbital holds 2 electrons, p holds 6 and d holds 10. Placing Copper's 29 electrons in that order gives 1s2 2s2 2p6 3s2 3p6 4s2 3d9, but copper is an exception.

Exception to the Aufbau rule. Filling orbitals in order would give 1s2 2s2 2p6 3s2 3p6 4s2 3d9, but the real configuration is 1s2 2s2 2p6 3s2 3p6 3d10 4s1 because a completely filled 3d¹⁰ is extra stable, so one 4s electron moves into 3d.

Copper at a glance

Atomic number29
SymbolCu
Atomic mass63.546 u
Group11
Period4
Blockd-block
CategoryTransition metal
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Other elements in group 11

ElementConfiguration
Silver[Kr] 4d10 5s1
Gold[Xe] 4f14 5d10 6s1
Roentgenium[Rn] 5f14 6d9 7s2